Explain why salt melts ice?

In short (click here for detailed version)

Salt melts ice by lowering the freezing point of water. In the presence of salt, water freezes at a temperature lower than 0 °C, resulting in the melting of the ice at that temperature.

Explain why salt melts ice?
In detail, for those interested!

First reason: Lowering of the freezing point

When salt is spread on ice, a unique phenomenon of lowering the freezing point occurs. Indeed, the salt dissolved in the water from the melting ice reduces the temperature at which the water will freeze again. This process is due to what is called cryoscopic lowering, a well-known physico-chemical property.

Normally, water freezes at 0 degrees Celsius. However, in the presence of salt, the temperature needed for ice to form decreases. Depending on the salt concentration, the freezing point of water can drop several degrees below zero. By dissolving the salt, the water becomes a mixture and the freezing point of this mixture is lower than that of pure water.

This decrease in freezing temperature is a crucial phenomenon in winter, as it allows roads to be less slippery thanks to the partial melting of the ice formed by the salt.

Second reason: Formation of a saline solution

When salt is spread on ice, it dissolves in the water from the melting ice. This dissolution of salt in water creates a saline solution. A saline solution is a combination of water and salt, where the salt is completely dissolved in the water. The formation of this saline solution changes the properties of water and prevents it from freezing at a normal freezing temperature. In fact, the presence of salt in the water lowers the freezing point of the water, making it more difficult for ice to form.

Third reason: Decrease in water viscosity

When salt is sprinkled on ice, it dissolves in the water from the melting ice. This saltwater has a lower viscosity than pure water. Indeed, the presence of salt particles dissolved in the water will disrupt the molecular structure of the water, thereby decreasing its viscosity. This decrease in viscosity leads to an increase in molecular mobility, making it easier for water molecules to move relative to each other. As a result, saltwater tends to flow more easily and spread over a larger surface area than pure water.

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Frequently Asked Questions (FAQ)

1

Are there more environmentally friendly alternatives to salt for melting ice on roads?

Yes, there are eco-friendly alternatives, such as sand, which improves traction without melting ice, or the use of biodegradable products made from sugar beets. However, these solutions may be more expensive or less effective at very low temperatures.

2

Does the salt used to melt ice affect vehicles?

Yes, regular exposure to road salt promotes corrosion, particularly on a vehicle's metal components. It is advisable to wash your car frequently during the winter to reduce this risk of corrosion.

3

At what temperature does salt lose its effectiveness on ice?

Salt (sodium chloride) is generally effective down to about -9 °C. Below this temperature, its effectiveness decreases significantly, so it is advisable to use alternatives such as calcium chloride or magnesium chloride.

4

Does salting the roads pose risks to domestic animals?

Yes, the salt used to de-ice roads can irritate the skin on the pads of pets' paws and cause digestive problems if ingested by licking. It is advisable to ensure that you clean your pet's paws after a walk on treated roads.

5

Why do we use salt instead of other substances to de-ice the roads?

Salt is widely used because it is economical, readily available in large quantities, easy to spread, and effective in lowering the freezing point of water. Despite these advantages, some places use alternatives such as calcium chloride, which is effective at even lower temperatures.

Natural Sciences : Chemistry

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