Explain why some gemstones change color in UV light.

In short (click here for detailed version)

Some gemstones change color in UV light due to the presence of impurities in their crystalline structure that are sensitive to ultraviolet rays. These impurities absorb UV light and emit a new color, causing the gemstone to change hue.

Explain why some gemstones change color in UV light.
In detail, for those interested!

Chemical composition of gemstones

Gemstones, such as diamonds, sapphires, emeralds, or rubies, are composed of different chemical elements that give them their unique characteristics. For example, diamonds are mainly made up of carbon, while sapphires and rubies are varieties of corundum composed mostly of alumina.

Other gemstones, like emeralds, contain silicon dioxide combined with traces of chromium or vanadium that give them their distinctive green color. Garnet, on the other hand, is composed of silicate and aluminum, with variations containing calcium, manganese, or iron.

Each gemstone has a specific chemical composition that influences its color, hardness, density, and optical properties. These chemical elements can also react uniquely to ultraviolet light, changing their appearance and color.

Effect of UV light on gemstones

Ultraviolet light (UV) can have an impact on the color of gemstones. Indeed, some minerals react in a particular way to UV light. This reaction can result in a temporary or permanent color change. Gemologists often use UV lamps to observe these reactions and identify treated or synthetic stones. Some minerals, such as diamonds, can emit fluorescence under UV light. This phenomenon can reveal information about the origin or treatment of a gemstone. Other stones, like topaz, may appear brighter or more intense under UV light. It is therefore important to take into account the effect of UV light when observing and analyzing gemstones.

Fluorescence and phosphorescence phenomenon.

Fluorescence and phosphorescence are optical phenomena that manifest themselves by the emission of light by certain materials after being exposed to a light source. Fluorescence is an immediate phenomenon that ceases as soon as the exposure to light stops. On the other hand, phosphorescence is a slower process that continues to emit light even after the exposure to the light source has stopped. These two phenomena are due to the materials' ability to absorb light energy and re-emit it as visible light. Gemstones that exhibit these characteristics are particularly appreciated for their unique and spectacular visual effect.

Color change mechanism

Gemstones change color under ultraviolet (UV) light due to various mechanisms. One of the most common mechanisms is the presence of impurities in the crystal structure of the stone. These impurities absorb UV light and re-emit light in the form of visible color. For example, some corundum crystals may contain iron, titanium, or chromium that absorb UV light and change the color of the stone.

Another mechanism for color change is the crystal structure of the stone itself. Some minerals, like alexandrite, have a crystal structure that allows them to change color depending on the wavelength of the incident light. This is due to a phenomenon called dichroism, where the stone appears different colors depending on the angle at which it is viewed.

Furthermore, some minerals can undergo chemical reactions under UV light, altering their molecular structure and therefore their color. For example, fluorite can change color under UV light due to the formation of color centers induced by ultraviolet radiation.

Finally, gemstones can also change color due to their isotopic composition. Certain chemical elements, like sulfur or bromine, can induce a color change in some gemstones due to isotopic variations that alter how light is absorbed and re-emitted.

In summary, the mechanisms of color change in gemstones under UV light are varied and complex, involving impurities, crystal structure, chemical reactions, and the isotopic composition of minerals. These fascinating phenomena contribute to the diversity of colors and optical properties of the gemstones that we admire.

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Frequently Asked Questions (FAQ)

1

What are the types of gemstones that react to UV light?

Precious gemstones such as amethyst, diamond, sapphire, or ruby can change color under the effect of UV light.

2

How does UV light influence the color of gemstones?

UV light can cause chemical reactions or alter the molecular structure of gemstones, resulting in a visible change in color.

3

What is the difference between fluorescence and phosphorescence in gemstones?

Fluorescence is a phenomenon where a gemstone emits light immediately under the effect of UV light, while phosphorescence is a delayed emission of light after the UV light exposure has stopped.

4

Do all precious stones react in the same way to UV light?

No, each type of gemstone reacts differently to UV light depending on its chemical composition and crystalline structure.

5

How do scientists study the color changes of gemstones under UV light?

Scientists use UV-Vis spectroscopy to analyze changes in the absorption and emission of light from gemstones under UV light.

Natural Sciences : Geology

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